Every meeting

28 Jun 2014 FIFA World Cup · Round of 16	Brazil	2–2 (aet, 3–2 pens)	Chile	D
28 Jun 2010 FIFA World Cup · 8th Finals	Brazil	3–0	Chile	W

This record covers meetings from 28 June 2010 onwards. Earlier games between these teams aren't on the site yet, so the all-time totals may be higher.
W / D / L from Brazil's side. Penalty shootouts count as draws.