Top scorers
| # | Player | Goals | Apps |
|---|---|---|---|
| 1 | Ronaldo Afonso | 3 | 14 |
| 1 | L. Leal | 3 | 12 |
| 3 | Iniesta | 1 | 7 |
| 3 | Joazhifel | 1 | 7 |
| 3 | Harramiz | 1 | 7 |
| 3 | Edmilson Viegas | 1 | 6 |
| 3 | Tinho | 1 | 5 |
| 3 | Dola | 1 | 4 |
| 3 | D. Silva | 1 | 3 |
Most caps
| # | Player | Caps | Goals |
|---|---|---|---|
| 1 | Ronaldo Afonso | 14 | 3 |
| 2 | L. Leal | 12 | 3 |
| 2 | Adjakson Ramos | 12 | 0 |
| 2 | J. Neves | 12 | 0 |
| 5 | Adjeil Neves | 11 | 0 |
| 5 | Eba Viegas | 11 | 0 |
| 7 | Ivonaldo Viegas | 10 | 0 |
| 8 | Ricardo Fernandes | 9 | 0 |
| 8 | G. D'Almeida | 9 | 0 |
| 10 | R. Fernandes | 8 | 0 |
| 10 | S. A. Andrade Male | 8 | 0 |
| 12 | Iniesta | 7 | 1 |
| 12 | Joazhifel | 7 | 1 |
| 12 | Harramiz | 7 | 1 |
| 12 | Gué | 7 | 0 |
| 12 | Kelve Semedo | 7 | 0 |
| 12 | Aldair | 7 | 0 |
| 12 | Mauro Vilhete | 7 | 0 |
| 19 | Edmilson Viegas | 6 | 1 |
| 19 | Vava Pequeno | 6 | 0 |
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Biggest wins
| 9 Oct 2019 AFCON Qualifiers |
 Mauritius |
1–3 | Sao Tome and Principe |
| 13 Oct 2025 World Cup Qualifiers (CAF) |
Sao Tome and Principe |
1–0 |  Malawi |
| 24 Mar 2022 AFCON Qualifiers |
Sao Tome and Principe |
1–0 | Mauritius |
| 13 Oct 2019 AFCON Qualifiers |
Sao Tome and Principe |
2–1 | Mauritius |
| 8 Oct 2015 World Cup Qualifiers (CAF) |
Sao Tome and Principe |
1–0 |  Ethiopia |
Heaviest defeats
| 13 Jun 2022 AFCON Qualifiers |
Sao Tome and Principe |
0–10 |  Nigeria |
| 10 Oct 2025 World Cup Qualifiers (CAF) |
Sao Tome and Principe |
0–6 |  Tunisia |
| 10 Sep 2023 AFCON Qualifiers |
Nigeria |
6–0 | Sao Tome and Principe |
| 17 Nov 2023 World Cup Qualifiers (CAF) |
Tunisia |
4–0 | Sao Tome and Principe |
| 9 Jun 2022 AFCON Qualifiers |
 Guinea-Bissau |
5–1 | Sao Tome and Principe |
| 13 Nov 2019 AFCON Qualifiers |
 Sudan |
4–0 | Sao Tome and Principe |
| 27 Mar 2026 AFCON Qualifiers |
Sao Tome and Principe |
0–3 | Ethiopia |
| 9 Sep 2025 World Cup Qualifiers (CAF) |
 Namibia |
3–0 | Sao Tome and Principe |
Records cover matches on this site: match sheets, plus season totals entered for older seasons. Ages use full dates of birth.